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Abstract Existing global volcanic radiative aerosol forcing estimates portray the period 700 to 1000 as volcanically quiescent, void of major volcanic eruptions. However, this disagrees with proximal Icelandic geological records and regional Greenland ice-core records of sulfate. Here, we use cryptotephra analyses, high-resolution sulfur isotope analyses, and glaciochemical volcanic tracers on an array of Greenland ice cores to characterise volcanic activity and climatically important sulfuric aerosols across the period 700 to 1000. We identify a prolonged episode of volcanic sulfur dioxide emissions (751–940) dominated by Icelandic volcanism, that we term the Icelandic Active Period. This period commences with the Hrafnkatla episode (751–763), which coincided with strong winter cooling anomalies across Europe. This study reveals an important contribution of prolonged volcanic sulfate emissions to the pre-industrial atmospheric aerosol burden, currently not considered in existing forcing estimates, and highlights the need for further research to disentangle their associated climate feedbacks. 

Abstract. We document the isotopic evolution of near-surface snow at the East Greenland Ice Core Project (EastGRIP) ice core site in northeast Greenland using a time-resolved array of 1 m deep isotope (δ18O, δD) profiles. The snow profiles were taken from May–August during the 2017–2019 summer seasons. An age–depth model was developed and applied to each profile, mitigating the impacts of stratigraphic noise on isotope signals. Significant changes in deuterium excess (d) are observed in surface snow and near-surface snow as the snow ages. Decreases in d of up to 5 ‰ occur during summer seasons after deposition during two of the three summer seasons observed. The d always experiences a 3 ‰–5 ‰ increase after aging 1 year in the snow due to a broadening of the autumn d maximum. Models of idealized scenarios coupled with prior work indicate that the summertime post-depositional changes in d (Δd) can be explained by a combination of surface sublimation, forced ventilation of the near-surface snow down to 20–30 cm, and isotope-gradient-driven diffusion throughout the column. The interannual Δd is also partly explained with isotope-gradient-driven diffusion, but other mechanisms are at work that leave a bias in the d record. Thus, d does not just carry information about source-region conditions and transport history as is commonly assumed, but also integrates local conditions into summer snow layers as the snow ages through metamorphic processes. Finally, we observe a dramatic increase in the seasonal isotope-to-temperature sensitivity, which can be explained solely by isotope-gradient-driven diffusion. Our results are dependent on the site characteristics (e.g., wind, temperature, accumulation rate, snow properties) but indicate that more process-based research is necessary to understand water isotopes as climate proxies. Recommendations for monitoring and physical modeling are given, with special attention to the d parameter.